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List of common compounds and their detectability
using the Standard UVIC® Mk II with a Krypton Lamp

 

Name
Detectable
Comments
Inorganic Compounds
Ammonia
Y
Good sensitivity
Hydrogen Suphide
Y
Limited sensitivity
Nitric Oxide
Y
Limited sensitivity
Nirogen Dioxide
Y
Moderate sensitivity
Argon
N
 
Carbon monoxide
N
 
Carbon dioxide
N
 
Hydrogen cyanide
N
 
Oxygen
N
Absorbs Kr radiation
Sulphur dioxide
N
 
Water vapour
N
Absorbs Kr radiation
Organic Compounds
Ethylene
Y
Good sensitivity
Ethanol
Y
Moderate sensitivity
Acetaldehyde
Y
Moderate sensitivity
Acetone
Y
Moderate sensitivity
Propylene
Y
Exceptional sensitivity
Iso-butylene
Y
Exceptional sensitivity
Methyl Acetate
Y
Moderate sensitivity
Iso-butane
Y
Moderate sensitivity
Benzene
Y
Good sensitivity
Toluene
Y
Good sensitivity
Xylenes (o,m + p)
Y
Good sensitivity
Styrene
Y
Good sensitivity
Naphthalene
Y
Good sensitivity
Methane
N
 
Ethane
N
 
Propane
N
 

 

Notes.

1. Comments #2 to #5 below apply to the performance of the UVIC® supplied in its standard form i.e. fitted with a krypton lamp. Comment #6 applies generally.

2. The UVIC® does not respond to the constituents of ‘normal’ clean air. However oxygen and water vapour both absorb the UV radiation to some extent and thus variations in absolute humidity will have a small effect on the calibration.

3. The UVIC® cannot detect the majority of commonly occurring inorganic compounds such as CO, CO2 and HCN. However it does exhibit good sensitivity to ammonia (NH3) which is very useful for some applications.

4. The UVIC® responds to a very large range of organic compounds. These include aliphatic and aromatic ethers, ketones, aldehydes and esters. In the vast majority of cases there will be a good response to compounds containing a C=C bond e.g. ethylene, propylene etc. Higher homologues of saturated aliphatic compounds are also detectable when the carbon chain lengths exceed 3 atoms.

5. The UVIC® also responds strongly to a wide range of industrially/domestically encountered compounds many of which are mixtures. These include:

i. Diesel and Gasoline Fuel vapour
ii. Turpentine and most other paint solvents
iii. Solvent based cleaning compounds
iv. Adhesives.
v. Solvents employed in the electronics, pharmaceutical and other industries.

6. The UVIC® responds to the total quantity of ionisable compounds present in the sampled airstream. Therefore it cannot distinguish between or among the compounds within a mixture. However if interest is centred on a known single compound then the UVIC® can readily be calibrated to provide a reasonably accurate (±10%) indication of the concentration. Sensitivity varies depending on the particular compound but generally concentrations in the region of 0.1 ppm V/V are detectable.

 

 

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